Journal article
2003
APA
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López-Torres, E., Mendiola, M., & Pastor, C. (2003). Chloro[5,6-diphenyl-1,2,4-triazine-3(2H)-thionato]dimethyltin(IV).
Chicago/Turabian
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López-Torres, E., M. Mendiola, and C. Pastor. “Chloro[5,6-DiPhenyl-1,2,4-Triazine-3(2H)-Thionato]DiMethylTin(IV)” (2003).
MLA
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López-Torres, E., et al. Chloro[5,6-DiPhenyl-1,2,4-Triazine-3(2H)-Thionato]DiMethylTin(IV). 2003.
BibTeX Click to copy
@article{e2003a,
title = {Chloro[5,6-diphenyl-1,2,4-triazine-3(2H)-thionato]dimethyltin(IV)},
year = {2003},
author = {López-Torres, E. and Mendiola, M. and Pastor, C.}
}
The reaction between dichlorodimethyltin(IV) and 5-methoxy-5,6-diphenyl-4,5-dihydro-2H-1,2,4-triazine-3-thione yields the title complex, [SnClMe2(C15H10N3S)]. The coordination sphere of the Sn atom is formed by the S, amine N and Cl atoms and two methyl groups, giving a pentacoordinate geometry. The distances Sn—N = 2.525 (2) A, Sn—S = 2.4671 (7) A, Sn—C = 2.109 (3) and 2.111 (4) A, and Sn—Cl = 2.4220 (7) A are in the ranges expected for this type of complex. The coordination mode of the triazinethione ligand results in a four-membered chelate ring.