ComBioCat group

Coordination compounds with biological and catalytic activity group

Chloro­[5,6-di­phenyl-1,2,4-triazine-3(2H)-thionato]­di­methyl­tin(IV)


Journal article


E. López-Torres, M. Mendiola, C. Pastor
2003

Semantic Scholar DOI
Cite

Cite

APA   Click to copy
López-Torres, E., Mendiola, M., & Pastor, C. (2003). Chloro­[5,6-di­phenyl-1,2,4-triazine-3(2H)-thionato]­di­methyl­tin(IV).


Chicago/Turabian   Click to copy
López-Torres, E., M. Mendiola, and C. Pastor. “Chloro­[5,6-Di­Phenyl-1,2,4-Triazine-3(2H)-Thionato]­Di­Methyl­Tin(IV)” (2003).


MLA   Click to copy
López-Torres, E., et al. Chloro­[5,6-Di­Phenyl-1,2,4-Triazine-3(2H)-Thionato]­Di­Methyl­Tin(IV). 2003.


BibTeX   Click to copy

@article{e2003a,
  title = {Chloro­[5,6-di­phenyl-1,2,4-triazine-3(2H)-thionato]­di­methyl­tin(IV)},
  year = {2003},
  author = {López-Torres, E. and Mendiola, M. and Pastor, C.}
}

Abstract

The reaction between di­chloro­di­methyl­tin(IV) and 5-meth­oxy-5,6-di­phenyl-4,5-di­hydro-2H-1,2,4-triazine-3-thione yields the title complex, [SnClMe2(C15H10N3S)]. The coordination sphere of the Sn atom is formed by the S, amine N and Cl atoms and two methyl groups, giving a pentacoordinate geometry. The distances Sn—N = 2.525 (2) A, Sn—S = 2.4671 (7) A, Sn—C = 2.109 (3) and 2.111 (4) A, and Sn—Cl = 2.4220 (7) A are in the ranges expected for this type of complex. The coordination mode of the triazine­thione ligand results in a four-membered chelate ring.


Share



Follow this website


You need to create an Owlstown account to follow this website.


Sign up

Already an Owlstown member?

Log in