ComBioCat group

Coordination compounds with biological and catalytic activity group

Three novel indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry


Journal article


Ana E. Platero‐Prats, M. Bernini, M. Medina, E. López-Torres, E. Gutiérrez‐Puebla, M. Monge, N. Snejko
2011

Semantic Scholar DOI
Cite

Cite

APA   Click to copy
Platero‐Prats, A. E., Bernini, M., Medina, M., López-Torres, E., Gutiérrez‐Puebla, E., Monge, M., & Snejko, N. (2011). Three novel indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry.


Chicago/Turabian   Click to copy
Platero‐Prats, Ana E., M. Bernini, M. Medina, E. López-Torres, E. Gutiérrez‐Puebla, M. Monge, and N. Snejko. “Three Novel Indium MOFs Derived from Diphenic Acid: Synthesis, Crystal Structures and Supramolecular Chemistry” (2011).


MLA   Click to copy
Platero‐Prats, Ana E., et al. Three Novel Indium MOFs Derived from Diphenic Acid: Synthesis, Crystal Structures and Supramolecular Chemistry. 2011.


BibTeX   Click to copy

@article{ana2011a,
  title = {Three novel indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry},
  year = {2011},
  author = {Platero‐Prats, Ana E. and Bernini, M. and Medina, M. and López-Torres, E. and Gutiérrez‐Puebla, E. and Monge, M. and Snejko, N.}
}

Abstract

Three In(III) MOFs based on diphenic acid and nitrogen-donor ancillary ligands were obtained as pure phases. Two of them have 1D chain structures, and the third forms 2D zig-zag layers. The different torsion angles adopted by the diphenic ligand along with the existence of several non-covalent interactions govern the crystal packing and determine the formation of a centrosymmetric one-dimensional compound (1) or a non-centrosymmetric helical chain-based compound (3). Reaction with 2,2′-bipyridyl under certain conditions leads also to the formation of two dimeric precursors (compounds 4 and 5). The topological study of all their nets is reported.


Share



Follow this website


You need to create an Owlstown account to follow this website.


Sign up

Already an Owlstown member?

Log in