ComBioCat group

Coordination compounds with biological and catalytic activity group

Three novel indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry


Journal article


Ana E. Platero‐Prats, M. Bernini, M. Medina, E. López-Torres, E. Gutiérrez‐Puebla, M. Monge, N. Snejko
2011

Semantic Scholar DOI
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APA   Click to copy
Platero‐Prats, A. E., Bernini, M., Medina, M., López-Torres, E., Gutiérrez‐Puebla, E., Monge, M., & Snejko, N. (2011). Three novel indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry.


Chicago/Turabian   Click to copy
Platero‐Prats, Ana E., M. Bernini, M. Medina, E. López-Torres, E. Gutiérrez‐Puebla, M. Monge, and N. Snejko. “Three Novel Indium MOFs Derived from Diphenic Acid: Synthesis, Crystal Structures and Supramolecular Chemistry” (2011).


MLA   Click to copy
Platero‐Prats, Ana E., et al. Three Novel Indium MOFs Derived from Diphenic Acid: Synthesis, Crystal Structures and Supramolecular Chemistry. 2011.


BibTeX   Click to copy

@article{ana2011a,
  title = {Three novel indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry},
  year = {2011},
  author = {Platero‐Prats, Ana E. and Bernini, M. and Medina, M. and López-Torres, E. and Gutiérrez‐Puebla, E. and Monge, M. and Snejko, N.}
}

Abstract

Three In(III) MOFs based on diphenic acid and nitrogen-donor ancillary ligands were obtained as pure phases. Two of them have 1D chain structures, and the third forms 2D zig-zag layers. The different torsion angles adopted by the diphenic ligand along with the existence of several non-covalent interactions govern the crystal packing and determine the formation of a centrosymmetric one-dimensional compound (1) or a non-centrosymmetric helical chain-based compound (3). Reaction with 2,2′-bipyridyl under certain conditions leads also to the formation of two dimeric precursors (compounds 4 and 5). The topological study of all their nets is reported.


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