Journal article
G. Mahmoudi, S. Seth, F. Zubkov, E. López-Torres, A. Bacchi, V. Stilinović, A. Frontera
Crystals, 2019
Crystals, 2019
Semantic Scholar
DOI
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APA
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Mahmoudi, G., Seth, S., Zubkov, F., López-Torres, E., Bacchi, A., Stilinović, V., & Frontera, A. (2019). Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands. Crystals.
Chicago/Turabian
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Mahmoudi, G., S. Seth, F. Zubkov, E. López-Torres, A. Bacchi, V. Stilinović, and A. Frontera. “Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands.” Crystals (2019).
MLA
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Mahmoudi, G., et al. “Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands.” Crystals, 2019.
BibTeX Click to copy
@article{g2019a,
title = {Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands},
year = {2019},
journal = {Crystals},
author = {Mahmoudi, G. and Seth, S. and Zubkov, F. and López-Torres, E. and Bacchi, A. and Stilinović, V. and Frontera, A.}
}
Abstract
Herein, we describe the synthesis and single crystal X-ray diffraction characterization of several Pb(II) complexes using Schiff base hydrazido-based ligands and different counterions (NO3−, I– and ClO4). In the three complexes reported in this work, the lead(II) metal exhibits a high coordination number (n > 8) and thus it is apparently not involved in tetrel bonding interactions. Moreover, the aromatic ligands participate in noncovalent interactions that play an important role in the formation of several supramolecular assemblies in the solid state of the three Pb(II) complexes. These assemblies have been analyzed by means of Hirshfeld surface analysis and DFT calculations.
