Journal article
E. López-Torres, D. G. Calatayud, A. Mendiola, C. Pastor, J. R. Procopio
2006
2006
Semantic Scholar
DOI
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APA
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López-Torres, E., Calatayud, D. G., Mendiola, A., Pastor, C., & Procopio, J. R. (2006). The First Complex of Benzilbis(thiosemicarbazone) acting as Bridging Ligand only through the Sulfur Atom.
Chicago/Turabian
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López-Torres, E., D. G. Calatayud, A. Mendiola, C. Pastor, and J. R. Procopio. “The First Complex of Benzilbis(Thiosemicarbazone) Acting as Bridging Ligand Only through the Sulfur Atom” (2006).
MLA
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López-Torres, E., et al. The First Complex of Benzilbis(Thiosemicarbazone) Acting as Bridging Ligand Only through the Sulfur Atom. 2006.
BibTeX Click to copy
@article{e2006a,
title = {The First Complex of Benzilbis(thiosemicarbazone) acting as Bridging Ligand only through the Sulfur Atom},
year = {2006},
author = {López-Torres, E. and Calatayud, D. G. and Mendiola, A. and Pastor, C. and Procopio, J. R.}
}
Abstract
The first complex with benzilbis(thiosemicarbazone) LH6 acting only as a bridge between two metallic centres through the sulfur atoms, was obtained from the reaction with methylmercury chloride. This complex shows a 1:2 ligand : mercury ratio and has been spectroscopically characterized and recrystallized in toluene. The ligand acts as a dianion, with an intermediate situation between cis and trans dispositions, and it is bonded to both methylmercury moieties through the sulfur atoms, giving a binuclear complex with linear CS coordination for the mercury atoms.
